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ChemInform Abstract: Oxidation of Benzylic and Allylic Alcohols with Cobalt(III) Acetate in Acetic Acid in the Presence and Absence of Sodium Bromide
- Source :
- ChemInform. 20
- Publication Year :
- 1989
- Publisher :
- Wiley, 1989.
-
Abstract
- Benzyl alcohol and its o-, m-, and p-substituted derivatives afforded fairly good yields of the corresponding benzaldehydes through a reaction with a Co(III)–NaBr system. With allylic alcohols, this system failed in a selective formation of unsaturated carbonyl compounds. In the latter cases, the products were effectively obtained by using a higher concentration of cobalt(III) acetate in the absence of NaBr.
Details
- ISSN :
- 09317597
- Volume :
- 20
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........d60ab062c73d76722d08c424bfe3b834