Room Temperature Synthesis, Crystal Structure, Water Sorption, and Thermal and Electronic Properties of {[Cu(phen)]2[Cu(phen)2]2Nb6O19}·24H2O

The new compound {[Cu(phen)]2[Cu(phen)2]2Nb6O19}·24H2O (I) (phen = 1,10-phenanthroline) was prepared under ambient conditions. The crystal structure is composed of the [Nb6O19]6– anion which is exp...