Back to Search
Start Over
Chemical and Electrochemical Synthesis, Structure, and Properties of Metal Chelates of Tridentate N,S-Containing Azomethinazo Ligands
- Source :
- Russian Journal of General Chemistry. 88:262-270
- Publication Year :
- 2018
- Publisher :
- Pleiades Publishing Ltd, 2018.
-
Abstract
- Novel Cu(II), Co(II), Ni(II), and Zn(II) complexes of 5-methyl-2-phenyl-4-[(4-phenylazo)anilinemethylylidene]- 2,4-dihydro-3H-pyrazole-3-thione and 5-methyl-4-[4-methyl-2-(4-methylphenylazo)anilinemethylylidene]- 2-phenyl-2,4-dihydro-3H-pyrazole-3-thione, i.e. ligands containing the phenylazo group in the ortho and para positions of the aniline fragment, were synthesized by the chemical and electrochemical methods. The complexes and ligands were characterized by IR, 1H NMR, X-ray absorption spectroscopy and magnetochemistry. The azo group of the ligands is not involved in coordination to the metal.
- Subjects :
- X-ray absorption spectroscopy
Absorption spectroscopy
010405 organic chemistry
General Chemistry
010402 general chemistry
Electrochemistry
01 natural sciences
0104 chemical sciences
Metal
chemistry.chemical_compound
Aniline
chemistry
Magnetochemistry
visual_art
Polymer chemistry
Proton NMR
visual_art.visual_art_medium
Chelation
Subjects
Details
- ISSN :
- 16083350 and 10703632
- Volume :
- 88
- Database :
- OpenAIRE
- Journal :
- Russian Journal of General Chemistry
- Accession number :
- edsair.doi...........d430af1f85ea43c4f057070ea91b839f