PALLADIUM AND NICKEL-CATALYZED PERFLUOROALKYLATION OF ALDEHYDES USING ZINC AND PERFLUOROALKYL HALIDES

Authors :: Nobuo Ishikawa
Neil J. O’Reilly
Masamichi Maruta
Source :: Chemistry Letters. 13:517-520
Publication Year :: 1984
Publisher :: The Chemical Society of Japan, 1984.
Abstract: A room temperature method for the conversion of perfluoroalkyl iodides to α-perfluoroalkyl carbinols under Pd or Ni catalysis is reported. The use of trifluoromethyl bromide provides an economical procedure for trifluoromethyl substituted carbinols.

Subjects :: chemistry.chemical_classification
Trifluoromethyl
chemistry.chemical_element
Halide
General Chemistry
Zinc
Medicinal chemistry
Aldehyde
Catalysis
Benzaldehyde
chemistry.chemical_compound
Nickel
chemistry
Organic chemistry
Palladium

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