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Ynamide Protonation-Initiated Cis -Selective Polyene Cyclization and Reaction Mechanism

Authors :
Xing Fan
Zhou Wang
Jiasheng Yao
Zhi-Xiang Yu
Junfeng Zhao
Chen-Long Li
Source :
CCS Chemistry. 4:2991-3001
Publication Year :
2022
Publisher :
Chinese Chemical Society, 2022.

Abstract

The diastereoselectivity of conventional polyene cyclization reactions is highly dependent on the configuration of the internal alkenes, where E-polyenes provide trans-decalins, while Z-polyenes of...

Details

ISSN :
20965745
Volume :
4
Database :
OpenAIRE
Journal :
CCS Chemistry
Accession number :
edsair.doi...........d33f793df39131a744523f34e3e49bbe
Full Text :
https://doi.org/10.31635/ccschem.021.202101331