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Diaquatris(nitrato-κ2O,O′)bis(4-pyridone-κO)lanthanum(III)

Authors :
Shan Gao
Zhao-Peng Deng
Hui Zhao
Li-Hua Huo
Source :
Acta Crystallographica Section E Structure Reports Online. 61:m2523-m2525
Publication Year :
2005
Publisher :
International Union of Crystallography (IUCr), 2005.

Abstract

In the mononuclear title compound, [La(NO3)3(C5H5NO)2(H2O)2], the LaIII atom is ten-coordinate, with a coordination polyhedron made up of the O atoms of two 4-pyridone ligands, six O atoms of three O,O′-chelating nitrate groups and two water mol­ecules, the polyhedron approximating a dodeca­hedron. The mol­ecule lies on a twofold rotation axis. A three-dimensional network structure is formed by hydrogen-bonding and π–π stacking inter­actions.

Details

ISSN :
16005368
Volume :
61
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........d2d5e2e5ee13fabbc948610a10c2849a