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Selective oxidation of optically active sec,sec-1,2-diols by dioxiranes. A practical method for the synthesis of homochiral .alpha.-hydroxy ketones in high optical purity
- Source :
- The Journal of Organic Chemistry. 58:3600-3601
- Publication Year :
- 1993
- Publisher :
- American Chemical Society (ACS), 1993.
-
Abstract
- By employing either dimethyldioxirane or its trifluoromethyl analog, the direct, high-yield conversion of one cyclic and three open chain optically sec,sec-1,2-diols to the corresponding α-hydroxy ketones in high optical yield has been achieved
Details
- ISSN :
- 15206904 and 00223263
- Volume :
- 58
- Database :
- OpenAIRE
- Journal :
- The Journal of Organic Chemistry
- Accession number :
- edsair.doi...........d0d4684365bc66d1b3417ffd08118a4d