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A simple strategy for spirocyclopentannulation of cyclic ketones. Formal total synthesis of (±)-acorone
- Source :
- Tetrahedron Letters. 37:1683-1686
- Publication Year :
- 1996
- Publisher :
- Elsevier BV, 1996.
-
Abstract
- A general and simple methodology for spirocyclopentannulation of cyclic ketones (or 4,4-disubstituted cyclopentenones from acyclic ketones) and its application in the synthesis of the spirodienone 7 via a prochiral precursor constituting a formal total synthesis of (+/-)-acorone (6), are described.
Details
- ISSN :
- 00404039
- Volume :
- 37
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........d0c7dd1256790f879b3021196ed029b1