Back to Search Start Over

Denitrogen alkene polymerization of bisdiazo compounds by copper(ii) catalysts

Authors :
Lijian Liu
Liqiong Liao
Longqiang Xiao
Yan Li
Source :
New Journal of Chemistry. 37:1874
Publication Year :
2013
Publisher :
Royal Society of Chemistry (RSC), 2013.

Abstract

Bisdiazo compounds were synthesized and underwent denitrogen alkene polymerization (DNAP) via the formation of an sp2 carbon bond in the presence of copper(II) catalysts, affording unsaturated polymers with molecular weights in the range of 2900 to 35 400 Da. The copper-catalyzed denitrogen alkene polymerization of bisdiazo compounds allows the efficient synthesis of unsaturated polyesters.

Subjects

Subjects :
chemistry.chemical_classification
Alkene
chemistry.chemical_element
General Chemistry
Polymer
Copper
Catalysis
Polyester
chemistry
Polymerization
Materials Chemistry
Organic chemistry
Carbon

Details

ISSN :
13699261 and 11440546
Volume :
37
Database :
OpenAIRE
Journal :
New Journal of Chemistry
Accession number :
edsair.doi...........d06bbf98bb84d38be0db5d0be55d14cf
Full Text :
https://doi.org/10.1039/c3nj00339f
Full Text Access
View/download PDF

Tools

Authors Abstract Subjects Details