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Spatial structure of the stereoisomers of 5-phenyl-5-oxo-2,4,6-trimethyl-1,3,5-dioxaphosphorinane

Authors :
S. Sh. Khetagurova
V. N. Smirnov
T. A. Zyablikova
O. A. Erastov
B. A. Arbuzov
R. A. Kadyrov
Source :
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:2061-2064
Publication Year :
1979
Publisher :
Springer Science and Business Media LLC, 1979.

Abstract

1. The stereoisomers of 5-phenyl-5-oxo-2,4,6-trimethyl-1,3,5-dioxaphosphorinane have been obtained. 2. The stereoisomers obtained have equatorial CH3 groups and differ with respect to the orientation of the P=O bond. 3. The stereoisomer with the equatorial orientation of the P=O bond predominates at equilibrium.

Details

ISSN :
15739171 and 05685230
Volume :
28
Database :
OpenAIRE
Journal :
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :
edsair.doi...........d068c3b2fdbeedda7aee2860cf216781
Full Text :
https://doi.org/10.1007/bf00947553