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Near-infrared fluorescent probe for ratiometric Al3+ signaling and imaging through combined PET and ICT mechanisms
- Source :
- Sensors and Actuators B: Chemical. 294:14-23
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- A porphyrin dimer (BPD) was introduced for selective detection of aluminum ions (Al3+) in a fully aqueous system. BPD produces a ratiometric emission profile in the near-infrared (NIR) region upon Al3+ complexation. The sensing mechanism involves photoinduced electron transfer (PET) and intramolecular charge transfer (ICT). The binding mode of BPD/Al3+ was fully examined based on spectroscopic titration, time-resolved fluorescence decay, NMR spectroscopy, mass spectrometry, and IR analyses. In aqueous media, the strong interaction between Lewis acid Al3+ and nitrogen atoms allows BPD to conquer the high energy barriers of the solvent for only Al3+, resulting in the high selectivity and low detection limit (2.65 × 10–8 M) of the probe. Practical applications of BPD for Al3+ monitoring in real samples and fluorescent prints were further investigated with satisfactory results. With its organic solvent-free sensing medium, good biocompatibility, and NIR ratiometric emission properties, the designed BPD probe is appropriate for ratiometric visualization of Al3+ in living cells.
- Subjects :
- 02 engineering and technology
010402 general chemistry
Mass spectrometry
Photochemistry
01 natural sciences
Photoinduced electron transfer
chemistry.chemical_compound
mental disorders
Materials Chemistry
Electrical and Electronic Engineering
Instrumentation
Detection limit
Aqueous solution
integumentary system
Chemistry
Near-infrared spectroscopy
Metals and Alloys
Nuclear magnetic resonance spectroscopy
021001 nanoscience & nanotechnology
Condensed Matter Physics
Fluorescence
Porphyrin
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
0210 nano-technology
Subjects
Details
- ISSN :
- 09254005
- Volume :
- 294
- Database :
- OpenAIRE
- Journal :
- Sensors and Actuators B: Chemical
- Accession number :
- edsair.doi...........d04b86203e6cec7a236289275f07663e