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Application of ferrocene-resorcinarene in silver nanoparticle synthesis
- Source :
- RSC Advances. 6:87128-87133
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- An amphiphilic resorcinarene with ferrocene groups at the lower rim has been applied as both reductant and stabilizer in the synthesis of colloidal silver nanoparticles. The structure of the nanocomposite obtained was investigated by transmission electron microscopy, atomic force microscopy, X-ray powder diffraction, dynamic light scattering, and UV and IR spectroscopy. In the nanocomposite, the silver nanoparticles are stabilized by the multi-layers formed by ferrocene-resorcinarene. The diameter of the nanoparticles is 20–30 nm while the size of the nanocomposite is about 45 nm. The nanoparticles demonstrate good catalytic activity for p-nitrophenol reduction. 40 nanomoles of the silver nanoparticles is sufficient to complete the reduction of p-nitrophenol over ten minutes.
- Subjects :
- Materials science
Nanocomposite
General Chemical Engineering
Inorganic chemistry
Nanoparticle
Infrared spectroscopy
02 engineering and technology
General Chemistry
Resorcinarene
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Silver nanoparticle
0104 chemical sciences
chemistry.chemical_compound
Dynamic light scattering
Ferrocene
chemistry
Chemical engineering
Transmission electron microscopy
0210 nano-technology
Subjects
Details
- ISSN :
- 20462069
- Volume :
- 6
- Database :
- OpenAIRE
- Journal :
- RSC Advances
- Accession number :
- edsair.doi...........cfcdd8d9e3f550722d6cc7cffbdb2226