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Iron porphyrin-nitrene complexes: preparation from 1,1-dialkylhydrazines. Electronic structure from NMR, Moessbauer, and magnetic susceptibility studies and crystal structure of the [tetrakis(p-chlorophenyl)porphyrinato][(2,2,6,6-tetramethyl-1-piperidyl)nitrene]iron complex
- Source :
- Journal of the American Chemical Society. 106:1699-1706
- Publication Year :
- 1984
- Publisher :
- American Chemical Society (ACS), 1984.
-
Abstract
- Preparation des complexes cites dans le titre a partir de la tetraphenylporphyrine, de la tetratolylporphyrine et de la tetra-para-chlorophenylporphyrine de fer(II). Obtention de ces complexes a l'etat cristallin. Structure du complexe avec (TpclPP) par diffraction RX et susceptibilite magnetique. Spectre de masse, spectre UV-visible, spectre IR, spectre Mossbauer, spectre RMN de H 1 et C 13 du complexe avec (TPP)
- Subjects :
- chemistry.chemical_classification
Stereochemistry
Nitrene
General Chemistry
Crystal structure
Electronic structure
Biochemistry
Porphyrin
Magnetic susceptibility
Catalysis
Crystallography
chemistry.chemical_compound
Colloid and Surface Chemistry
chemistry
X-ray crystallography
Molecule
Inorganic compound
Subjects
Details
- ISSN :
- 15205126 and 00027863
- Volume :
- 106
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi...........cfc632ad77d519e0c8ed53f0d80e61c2
- Full Text :
- https://doi.org/10.1021/ja00318a024