Alpine catena response to nitrogen deposition and its effect on the aquatic system

Alpine areas are vulnerable to nitrogen (N) deposition because of low N-buffering capacity and limited ability to resist change. The objective of the study was to assess if >30 years of N deposition have resulted in a decline in exchangeable base cations (CB) coupled with an increase of exchangeable aluminum (Al). We used soil and stream data sampled between 1982 and 2015 at Green Lakes Valley, Colorado Front Range to evaluate the change in an alpine catena. The CB in the surface horizons of the summit position decreased significantly from 45 cmolc kg−1 in 1982 to 2.3 cmolc kg−1 in 2015, while the exchangeable Al increased from 0.09 cmolc kg−1 to 0.7 cmolc kg−1 in the summit and from 8.9 cmolc kg−1 to 10.5 cmolc kg−1 in the toeslope. Spatiotemporal distribution of soil moisture along the catena exhibited the lowest values during the winter months because the temperature was below freezing. The soil moisture increased in early spring as soil-temperature rose. A Seasonal Kendall test (SK) showed that the soil moisture decreased along the catena by −0.007 m3 m−3 yr−1(P