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Supercritical synthesis and topological analysis of K5U5O17(OH)
- Source :
- CrystEngComm. 19:3499-3505
- Publication Year :
- 2017
- Publisher :
- Royal Society of Chemistry (RSC), 2017.
-
Abstract
- High quality single crystals of the monoclinic phase K5U5O17(OH) were synthesized via a hydrothermal method utilizing the supercritical regime of water. The structure of K5U5O17(OH) is isotypic with the Na phase, Na5U5O17(OH), however crystallizes in a slightly different space group due to size effects. K5U5O17(OH) has the same sheet-anion structure as the Na analog, whose topology is analyzed here for the first time. K5U5O17(OH) shows fluorescence typical for uranyl species.
- Subjects :
- Chemistry
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
Uranyl
Topology
01 natural sciences
Fluorescence
Supercritical fluid
Hydrothermal circulation
0104 chemical sciences
Crystallography
chemistry.chemical_compound
Phase (matter)
General Materials Science
0210 nano-technology
Topology (chemistry)
Monoclinic crystal system
Subjects
Details
- ISSN :
- 14668033
- Volume :
- 19
- Database :
- OpenAIRE
- Journal :
- CrystEngComm
- Accession number :
- edsair.doi...........cf9f3545fccba8764b7b337a2aa7ae7c