Substitution of Acyl for Acetyl with N-Acylbenzotriazoles Catalyzed by Samarium Triiodide

Authors :: Xiaofei Jia
Xiaoxia Wang
Xuefei Zou
Guanqun Xie
Source :: ChemInform. 38
Publication Year :: 2007
Publisher :: Wiley, 2007.
Abstract: Catalyzed by samarium triiodide (SmI3), substitution of acyl with N‐acylbenzotriazoles for acetyl in acetoacetic esters and acetylacetone proceeds smoothly under neutral conditions in open air, affording the corresponding β‐keto esters and β‐diketones in good yields.

Subjects :: Substitution reaction
Samarium
chemistry.chemical_compound
chemistry
Acetylacetone
Substitution (logic)
chemistry.chemical_element
General Medicine
Triiodide
Medicinal chemistry
Catalysis
Open air

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