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Efficient and stable inverted planar perovskite solar cells using dopant-free CuPc as hole transport layer
- Source :
- Electrochimica Acta. 273:273-281
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- Flexible perovskite solar cells (PSCs) such as inverted PSCs are gaining increasing attention due to their wide range of potential applications, while the selection of stable, high conductivity and energy level suitable hole transport layers (HTLs) is still challenging. Here we introduce dopant-free copper phthalocyanine (CuPc) as HTL in inverted planar PSCs, and demonstrate improved photovoltaic performance and increased stability with high reproducibility and uniformity compared to the PEDOT:PSS based devices. The champion efficiency of PSCs is achieved by 15.4% on rigid substrates and 12.8% on flexible substrates, respectively. The flexible devices also exhibit excellent bending stability, retaining ∼85% of the original power conversion efficiency (PCE) after 3000 bending cycles at r = 5 mm without encapsulation. Our study provides a new strategy for fabricating cost-effective, scalable and flexible PSCs with high efficiency, little hysteresis, and excellent stability.
- Subjects :
- Materials science
Dopant
business.industry
High conductivity
General Chemical Engineering
Photovoltaic system
Energy conversion efficiency
Hole transport layer
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Planar
PEDOT:PSS
Copper phthalocyanine
Electrochemistry
Optoelectronics
0210 nano-technology
business
Subjects
Details
- ISSN :
- 00134686
- Volume :
- 273
- Database :
- OpenAIRE
- Journal :
- Electrochimica Acta
- Accession number :
- edsair.doi...........cd8d16e4a92f97cb55295c45143ac1f7