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'Sweeping' Ortho Substituents Drive Desolvation and Overwhelm Electronic Effects in Nd3+ Chelation: A Case of Three Aryldithiophosphinates

Authors :
Lei Xu
Ping Yang
Jing Chen
Ning Pu
Jenifer C. Shafer
Chao Xu
Enrique R. Batista
Taoxiang Sun
Jing Su
Source :
Inorganic Chemistry. 59:161-171
Publication Year :
2019
Publisher :
American Chemical Society (ACS), 2019.

Abstract

Bis[o-(trifluoromethyl)phenyl]dithiophosphinate is a sulfur-donating ligand capable of providing the largest reported trivalent lanthanide (Ln3+)–actinide (An3+) group separation factors. Literatur...

Details

ISSN :
1520510X and 00201669
Volume :
59
Database :
OpenAIRE
Journal :
Inorganic Chemistry
Accession number :
edsair.doi...........cd400ec195be133c883b337570212fe3