Back to Search Start Over

Direct synthesis of N-phosphanyl-heterocyclic carbenes

Authors :
Aleksandr N. Kostyuk
Igor I. Pervak
Anatolii P. Marchenko
Andrei A. Tolmachev
Heorgii N. Koidan
Anastasiia N. Huryeva
Evgeniy V. Zarudnitskii
Source :
Tetrahedron Letters. 53:494-496
Publication Year :
2012
Publisher :
Elsevier BV, 2012.

Abstract

A direct method for the synthesis of N -phosphanyl-heterocyclic carbenes is described. The method is based on the reaction of lithium imidazolides and benzimidazolides having a bulky alkyl group at the nitrogen atom with di( tert -butyl)chlorophosphine leading directly to the carbenes.

Details

ISSN :
00404039
Volume :
53
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........ccbbf1b312a73f5a518095a62f1ebac4