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Correlating Mechanical Sensitivity with Spin Transition in the Explosive Spin Crossover Complex [Fe(Htrz)3]n[ClO4]2n

Authors :
Gary F. Angles-Tamayo
Tammie Nelson
Eric J. Schelter
Jacqueline M. Veauthier
David E. Chavez
Thuy-Ai D. Nguyen
Ekaterina Lapsheva
Thomas W. Myers
Source :
Journal of the American Chemical Society. 142:4842-4851
Publication Year :
2020
Publisher :
American Chemical Society (ACS), 2020.

Abstract

Spin crossover complexes are known to undergo bond length, volume, and enthalpy changes during spin transition. In an explosive spin crossover complex, these changes could affect the mechanical and...

Details

ISSN :
15205126 and 00027863
Volume :
142
Database :
OpenAIRE
Journal :
Journal of the American Chemical Society
Accession number :
edsair.doi...........cbf1f6bbeb9d5d4973526bd48b9de8b5