Back to Search Start Over

ChemInform Abstract: Remarkably Complex and Unpredictable Cyclization and Rearrangement Reactions of Cations Derived from Unsaturated Oxiranes

Authors :
Bryan E. Roberts
E. J. Corey
Source :
ChemInform. 29
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

Lewis-acid catalyzed reactions of unsaturated epoxides 1 and 2 afford the unprecedented products 3 and 5, respectively. Mechanistic pathways for these reactions are presented (Schemes 2 and 4) along with a more fundamental analysis.

Details

ISSN :
15222667 and 09317597
Volume :
29
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........cae92669dd0ba1ff915113e426a34a47
Full Text :
https://doi.org/10.1002/chin.199814051