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Studies on redox and axial ligand properties of Meso-Mn(III) porphyrin by cyclic voltammetry and UV–Visible spectrophotometry
- Source :
- Materials Today: Proceedings. 47:933-937
- Publication Year :
- 2021
- Publisher :
- Elsevier BV, 2021.
-
Abstract
- Manganese (III) complex with meso-5,10,15,20-Tetrakis(2,5-dimethoxy-phenyl) porphyrin, Mn[T(2,5-(OCH3)2)PP], has been prepared utilizing meso-5,10,15,20-Tetrakis(2,5-dimethoxyphenyl)porphyrin, [T(2,5-(OCH3)2)PP], and Manganese (II) acetate by complexation method. The prepared complex is characterized by UV–Vis spectrophotometric and cyclic voltammetric (CV) studies. The formation of Mn(III) porphyrin complex may be due to a significant metal-porphyrin π interaction. In Mn(III) porphyrin, Mn is in high spin d4 configuration. The strongest σ bonding amongst the Mn and the porphyrin with four pyrrole nitrogen donors is responsible for the octahedral geometry. The change in geometry of the complex from octahedral to tetragonal is due to the presence of two axial amines supplied by the addition of secondary amine. Addition of primary amine leads to the formation of square pyramidal Mn(II) porphyrin, wherein the central metal atom is in high-spin d5 configuration with the occupied d(x2-y2) orbital whose orbital energy is low. This indicates that Mn(III) will be out of the plane of porphyrin. The change in the oxidation state of the central manganese atom and shape of the complex were supported by UV–Vis spectrophotometric studies. Cyclic voltammogram confirmed the oxidation and reduction behaviors of Mn porphyrin complex and the oxidation of Mn(III) into Mn(IV) at 0.3209 V.
- Subjects :
- 010302 applied physics
Ligand
chemistry.chemical_element
02 engineering and technology
Manganese
021001 nanoscience & nanotechnology
01 natural sciences
Porphyrin
Square pyramidal molecular geometry
Metal
chemistry.chemical_compound
Crystallography
chemistry
Oxidation state
visual_art
0103 physical sciences
Octahedral molecular geometry
visual_art.visual_art_medium
Cyclic voltammetry
0210 nano-technology
Subjects
Details
- ISSN :
- 22147853
- Volume :
- 47
- Database :
- OpenAIRE
- Journal :
- Materials Today: Proceedings
- Accession number :
- edsair.doi...........c9dc34103c784a55fa8e0849c1d1df5b