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Electrodeposition of photocatalytic AlInSb semiconductor alloys in the Lewis acidic aluminum chloride−1-ethyl-3-methylimidazolium chloride room-temperature ionic liquid
- Source :
- Thin Solid Films. 516:6220-6225
- Publication Year :
- 2008
- Publisher :
- Elsevier BV, 2008.
-
Abstract
- The electrodeposition of AlIn, AlSb, and AlInSb alloys was examined at copper rotating wire electrodes in the Lewis acidic 66.7–33.3 mol.% (m/o) aluminum chloride–1–ethyl–3–methylimidazolium chloride room-temperature ionic liquid. The Sb content in the AlSb binary electrodeposits depended on the applied current density, but the In content in the AlIn alloys was quite low, ∼ 1 at.% (a/o), and independent of the current density. Variation of the partial current densities for the In and Sb during AlInSb deposition suggested that the deposition of a second phase rich in In and Sb, possibly InSb, occurs simultaneously at higher applied current densities. However, no X-ray diffraction patterns are apparent in these deposits other than that for face-centered cubic Al. Thus, the AlInSb deposit most likely consists of a non-equilibrium mixture of Al x In y Sb 100– x – y and amorphous or nanocrystalline InSb. The AlInSb alloy semiconductor deposits prepared during this investigation exhibited photocatalytic behavior and could catalyze the photodecomposition of water under illumination with visible light.
- Subjects :
- Materials science
1-Ethyl-3-methylimidazolium chloride
Alloy
Inorganic chemistry
Metals and Alloys
chemistry.chemical_element
Surfaces and Interfaces
engineering.material
Chloride
Copper
Nanocrystalline material
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Amorphous solid
chemistry.chemical_compound
chemistry
Ionic liquid
Materials Chemistry
engineering
medicine
Partial current
medicine.drug
Subjects
Details
- ISSN :
- 00406090
- Volume :
- 516
- Database :
- OpenAIRE
- Journal :
- Thin Solid Films
- Accession number :
- edsair.doi...........c96a02623616b1a6e76bc228809d3747