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catena-Poly[[[diacetonitrilesilver(I)]-μ-2,11-dithia[3.3]paracyclophane-κ2S:S′] hydrogenoctafluoroadipate]

Authors :
Hisashi Konaka
Takayoshi Kuroda-Sowa
Gui Ling Ning
Shu Qin Liu
Megumu Munakata
Masahiko Maekawa
Yusaku Suenaga
Source :
Acta Crystallographica Section E Structure Reports Online. 60:m865-m867
Publication Year :
2004
Publisher :
International Union of Crystallography (IUCr), 2004.

Abstract

The title compound, {[Ag(C16H16S2)(C2H3N)2](C6HF8O4)}n, forms two infinite chains, which are approximately perpendicular to each other. One chain consists of [Ag(C16H16S2)(C2H3N)2]nn+, and the other is formed from HOFA− (HOFA− is hydrogen octa­fluoro­adipate) units via Oc—H⋯Oc (c is carboxy) hydrogen-bonding interactions, with an H⋯A distance of 1.66 (5) A. Each silver(I) cation lies on a crystallographic twofold rotation axis and has a tetrahedral geometry, defined by two N atoms belonging to two aceto­nitrile mol­ecules and two S atoms from two 2,11-di­thia­[3.3]­para­cyclo­phane mol­ecules. The cyclophanes have inversion symmetry.

Details

ISSN :
16005368
Volume :
60
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........c93a644870f49c51edfc88ff43a1b0ce