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catena-Poly[[[diacetonitrilesilver(I)]-μ-2,11-dithia[3.3]paracyclophane-κ2S:S′] hydrogenoctafluoroadipate]
- Source :
- Acta Crystallographica Section E Structure Reports Online. 60:m865-m867
- Publication Year :
- 2004
- Publisher :
- International Union of Crystallography (IUCr), 2004.
-
Abstract
- The title compound, {[Ag(C16H16S2)(C2H3N)2](C6HF8O4)}n, forms two infinite chains, which are approximately perpendicular to each other. One chain consists of [Ag(C16H16S2)(C2H3N)2]nn+, and the other is formed from HOFA− (HOFA− is hydrogen octa­fluoro­adipate) units via Oc—H⋯Oc (c is carboxy) hydrogen-bonding interactions, with an H⋯A distance of 1.66 (5) A. Each silver(I) cation lies on a crystallographic twofold rotation axis and has a tetrahedral geometry, defined by two N atoms belonging to two aceto­nitrile mol­ecules and two S atoms from two 2,11-di­thia­[3.3]­para­cyclo­phane mol­ecules. The cyclophanes have inversion symmetry.
Details
- ISSN :
- 16005368
- Volume :
- 60
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Structure Reports Online
- Accession number :
- edsair.doi...........c93a644870f49c51edfc88ff43a1b0ce