Spin dependence of d5/2 neutron configurations in the wave functions of 92,94Zr from g-factor measurements

g factors of the 2 + 1 and 4 + 1 states in 92,94 Zr have been measured via Coulomb excitation of isotopically pure 92,94 Zr beams in inverse kinematics in combination with the transient field technique. The high precision results, g ( 92 Zr; 2 + 1 ) = −0.180(10) and g ( 94 Zr; 2 + 1 ) = −0.329(15) as well as the new data on the 4 + 1 state, g ( 92 Zr; 4 + 1 ) = −0.50(11), provide, for the first time, clear evidence of the dominant role of d 5/2 neutrons in the wave functions of these nuclei just above the N =50 shell closure. Moreover, the data imply increased purity of the d 5/2 neutron component in the wave function with increasing spin.