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Humidity dependence of the oxidation of carbon monoxide adsorbed on Pt/C and PtRu/C electrocatalysts
- Source :
- Physical Chemistry Chemical Physics. 4:2337-2340
- Publication Year :
- 2002
- Publisher :
- Royal Society of Chemistry (RSC), 2002.
-
Abstract
- The oxidation of carbon monoxide adsorbed on a supported Pt (30 wt.% and 60 wt.% Pt/C) or PtRu (30 wt.% and 45 wt.% PtRu/C) gas diffusion electrode at various humidities and temperatures was investigated in an actual PEFC configuration. It is shown that the adsorbed CO-stripping potential on Pt/C and PtRu/C decreased with an increase in the humidity of the fuel until the dew point of the fuel reached the cell temperature. The CO-stripping potential of the 45 wt.% PtRu/C is lower and less sensitive to the humidity of the fuel than that of the 30 wt.% PtRu, which suggested that the PtRu/C with a higher catalyst density adsorbs water more strongly, even under lower humidity conditions.
Details
- ISSN :
- 14639084 and 14639076
- Volume :
- 4
- Database :
- OpenAIRE
- Journal :
- Physical Chemistry Chemical Physics
- Accession number :
- edsair.doi...........c8291ea7df07ef51f1a9be97f7e50ce4