Back to Search Start Over

catena-Poly[[bis(di-4-pyridylamine-κN)(terephthalato-κ2 O,O′)nickel(II)]-μ-di-4-pyridylamine-κ2 N:N′]

Authors :
Maxwell A. Braverman
Robert L. LaDuca
Source :
Acta Crystallographica Section E Structure Reports Online. 63:m2780-m2780
Publication Year :
2007
Publisher :
International Union of Crystallography (IUCr), 2007.

Abstract

In the title compound, [Ni(C8H4O4)(C10H9N3)3] n , an NiII atom with octahedral coordination is bound by one chelating terephthalate (tp) dianion, two monodentate di-4-pyridylamine (dpa) ligands, and two bridging dpa ligands. These link the Ni atoms into one-dimensional [Ni(tp)(dpa)3] n coordination polymer chains that propagate along the b-axis direction. Interweaving pairs of chains stack in three dimensions via N—H...O hydrogen bonding.

Details

ISSN :
16005368
Volume :
63
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........c77fcb03d4608b1bbaad55b08d046b52