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Organocatalytic Oxidative Dimerization of Alcohols to Esters

Authors :
Alex M. Szpilman
Hila Toledo
A. I. Abramovich
Evgeni Pisarevsky
Source :
Synlett. 23:2261-2265
Publication Year :
2012
Publisher :
Georg Thieme Verlag KG, 2012.

Abstract

2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric ­esters at 1–2 mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55–99%.

Details

ISSN :
14372096 and 09365214
Volume :
23
Database :
OpenAIRE
Journal :
Synlett
Accession number :
edsair.doi...........c5ca137f2e8f97a4c9eb2dde8888ff90
Full Text :
https://doi.org/10.1055/s-0032-1317018