Back to Search
Start Over
Thermodynamic heat-transfer phenomena in nanostructured glassy substances: a comparative study on g-As5Se95 and g-As55Se45
Thermodynamic heat-transfer phenomena in nanostructured glassy substances: a comparative study on g-As5Se95 and g-As55Se45
- Source :
- Journal of Thermal Analysis and Calorimetry. 148:2265-2271
- Publication Year :
- 2023
- Publisher :
- Springer Science and Business Media LLC, 2023.
-
Abstract
- Nanostructurization-driven responses in calorimetric heat-transfer phenomena are compared for glassy arsenoselenides at different levels of their molecular network organization, namely in high-polymerized g-As5Se95 and low-polymerized g-As55Se45, employing multifrequency temperature-modulated DSC-TOPEM® method complemented with Raman scattering microspectroscopy. It is shown that high-polymerized network composed of AsSe3 pyramids interlinked by Se chains with small number of Se8 molecular units decoupled from this network prevails in melt-quenched and nanomilling-derived g-As5Se95. Transition to more polymerized network due to incorporation of destroyed Se8 molecules into glass backbone occurs in this glass under nanostructurization. As a result, nanostructurization-driven calorimetric response in g-As5Se95 dominates by size-induced glass-transition temperature depression. The low-polymerized structure of g-As55Se45 is built of As–Se network enriched with tetra-arsenic selenide molecular units decoupled from this network. Molecular-to-network transition owing to nanomilling-driven destruction of these cage molecules and their incorporation into newly polymerized glass-forming backbone occurs in g-As55Se45 resulting in strong increase in calorimetric glass-transition temperature.
- Subjects :
- Physical and Theoretical Chemistry
Condensed Matter Physics
Subjects
Details
- ISSN :
- 15882926 and 13886150
- Volume :
- 148
- Database :
- OpenAIRE
- Journal :
- Journal of Thermal Analysis and Calorimetry
- Accession number :
- edsair.doi...........c5a6ee24eef5c67c07dc69b665e33a10
- Full Text :
- https://doi.org/10.1007/s10973-022-11913-4