The Effect of Metal Type on Hydrodeoxygenation of Phenol Over Silica Supported Catalysts

Authors :: Fabio B. Noronha
Lisiane V. Mattos
Camila A. Teles
Jerusa R. de Lima
Daniel E. Resasco
Raimundo C. Rabelo-Neto
Source :: Catalysis Letters. 146:1848-1857
Publication Year :: 2016
Publisher :: Springer Science and Business Media LLC, 2016.
Abstract: Different metals supported on SiO2 were tested for the hydrodeoxygenation of phenol. For Pt/SiO2, Pd/SiO2 and Rh/SiO2 catalysts, phenol is mainly tautomerized, followed by hydrogenation of the aromatic ring. The direct dehydroxylation of phenol followed by hydrogenolysis is favored over more oxophilic metals (Ru, Co and Ni).

Subjects :: 010405 organic chemistry
General Chemistry
010402 general chemistry
Ring (chemistry)
01 natural sciences
Tautomer
Catalysis
0104 chemical sciences
Metal
chemistry.chemical_compound
chemistry
Hydrogenolysis
visual_art
visual_art.visual_art_medium
Phenol
Organic chemistry
Hydrodeoxygenation
Organometallic chemistry

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