ChemInform Abstract: Formal Regiocontrolled Hydroboration of Unbiased Internal Alkynes via Borylation/Allylic Alkylation of Terminal Alkynes

Authors :: Pablo Mauleón
Ramón Gómez Arrayás
Abraham L. Moure
Juan C. Carretero
Source :: ChemInform. 44
Publication Year :: 2013
Publisher :: Wiley, 2013.
Abstract: This preparation of 1,2-disubstituted vinylboranes is based on a directed borylation of terminal alkynes followed by Cu-catalyzed allylic alkylation with Grignard reagents.

Subjects :: Tsuji–Trost reaction
Hydroboration
Terminal (electronics)
Chemistry
organic chemicals
food and beverages
General Medicine
Combinatorial chemistry
Borylation

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