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Modification of graphene oxide with acrylate phosphorus monomer via thiol-Michael addition click reaction to enhance the anti-corrosive performance of waterborne epoxy coatings
- Source :
- Progress in Organic Coatings. 146:105724
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- To develop a convenient way to functionalize graphene oxide (GO) for corrosion protective coatings, a commercial acrylate phosphorus functional monomer (SIPOMER PAM100) was used to modify thiol-terminated GO via thiol-Michael addition click reaction. Subsequently, PAM100 modified GO (PGO) was introduced to waterborne epoxy coating as a nanofiller for anticorrosion reinforcement. The anticorrosive performance of PGO/WEP nanocomposite coatings was evaluated by electrochemical impedance spectroscopy (EIS). Results obtained from FT-IR, XRD, Raman, SEM and SEM-EDS show that PAM100 is successfully grafted to the surface of GO using γ-Mercaptopropyl triethoxysilane (KH-580) as a bridge molecule. It is clear that PGO distributes homogenously within WEP matrix from SEM images. After 40-day exposure to 3.5 wt.% NaCl solution, the |Z|0.01Hz of blank WEP suffers a serious decrease (from 9.83 × 107 Ω·cm2 to 4.93 × 106 Ω·cm2) while PGO/WEP has a relatively smaller change in |Z|0.01Hz (from 1.35 × 108 Ω·cm2 to 2.91 × 107 Ω·cm2). It demonstrated that PGO/WEP coating presents a superior corrosion resistance performance.
- Subjects :
- Materials science
General Chemical Engineering
Oxide
02 engineering and technology
engineering.material
010402 general chemistry
01 natural sciences
Corrosion
chemistry.chemical_compound
Coating
Materials Chemistry
Acrylate
Nanocomposite
Organic Chemistry
Epoxy
021001 nanoscience & nanotechnology
0104 chemical sciences
Surfaces, Coatings and Films
Dielectric spectroscopy
Chemical engineering
chemistry
visual_art
Triethoxysilane
visual_art.visual_art_medium
engineering
0210 nano-technology
Subjects
Details
- ISSN :
- 03009440
- Volume :
- 146
- Database :
- OpenAIRE
- Journal :
- Progress in Organic Coatings
- Accession number :
- edsair.doi...........c380995b9bb4b1f877e6bf94bd288357