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Electronic Structure of Vertically Aligned Mn-Doped CoFe2O4 Nanowires and Their Application as Humidity Sensors and Photodetectors
- Source :
- The Journal of Physical Chemistry C. 113:7085-7090
- Publication Year :
- 2009
- Publisher :
- American Chemical Society (ACS), 2009.
-
Abstract
- Vertically aligned CoFe2O4 and 10% Mn-doped CoFe2O4 nanowires were synthesized by the gas-phase reduction/substitution reaction of pregrown α-Fe2O3 nanowires. They consisted of perfect single-crystalline cubic structures grown along the [110] direction. The increase of the lattice constant provides evidence for the effective Mn substitution. We investigated their electronic structures using X-ray absorption spectroscopy and X-ray magnetic circular dichroism. The results suggest that as the Mn substitutes, Mn2+/Mn3+ ions would occupy the octahedral (Oh) sites, Mn4+ ions form at the tetrahedral (Td) sites, and a fraction of the Co2+ ions migrate from the Oh sites to the Td sites. The effective Mn substitution can increase the hole concentration, which makes it possible to develop humidity sensors operating at room temperature. Furthermore, it induces high photocurrents upon irradiation of visible light.
- Subjects :
- Materials science
Absorption spectroscopy
Magnetic circular dichroism
Analytical chemistry
Nanowire
Nanotechnology
Electronic structure
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ion
General Energy
Lattice constant
Octahedron
Physical and Theoretical Chemistry
Visible spectrum
Subjects
Details
- ISSN :
- 19327455 and 19327447
- Volume :
- 113
- Database :
- OpenAIRE
- Journal :
- The Journal of Physical Chemistry C
- Accession number :
- edsair.doi...........c25aa69da333727c82c63f1048a5a128