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ChemInform Abstract: Second-Generation Fluorous Chiral (Salen) Manganese Complexes

Authors :
Silvio Quici
Amedea Manfredi
Gianluca Pozzi
Fernando Montanari
Marco Cavazzini
Source :
ChemInform. 32
Publication Year :
2001
Publisher :
Wiley, 2001.

Abstract

Sterically hindered chiral (salen)manganese complexes bearing long perfluoroalkyl substituents are synthesized and successfully employed as catalysts in the enantioselective (ee = 50–87%) epoxidation of alkenes under fluorous biphasic conditions.

Subjects

Subjects :
Steric effects
chemistry
Polymer chemistry
Enantioselective synthesis
chemistry.chemical_element
General Medicine
Manganese
Catalysis

Details

ISSN :
15222667 and 09317597
Volume :
32
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........c24ec8033e5ca48ed5acfb67f81a8ff1
Full Text :
https://doi.org/10.1002/chin.200105030
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