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Trimerization of 1,4-Dichloro-2-butyne to 5-(1′-Chlorovinyl)-1,2,3,4,5-pentachloromethylcyclopentadiene Catalyzed by Palladium Complex

Authors :
Jin-Sheng Cheng
Qun-Jian Zhang
Huanfeng Jiang
Jin-Heng Li
Xiao-Yue Ouyang
Source :
Synthetic Communications. 33:3003-3008
Publication Year :
2003
Publisher :
Informa UK Limited, 2003.

Abstract

5-(1′-Chlorovinyl)-1,2,3,4,5-pentachloromethylcyclopentadiene was prepared regioselectively via palladium chloride-catalyzed [2+2+1] trimerization of 1,4-dichloro-2-butyne in excellent yield.

Details

ISSN :
15322432 and 00397911
Volume :
33
Database :
OpenAIRE
Journal :
Synthetic Communications
Accession number :
edsair.doi...........c1d6a7acf6dbd11ac8847dba5c1d816a
Full Text :
https://doi.org/10.1081/scc-120022474