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Development of a new continuous dissolution apparatus with a hydrophobic membrane for superheavy element chemistry

Authors :
Y. Oshimi
Y. Nagame
Sunao Miyashita
T. Koyama
Hans Vigeland Lerum
Atsushi Tanaka
N. S. Gupta
H. Haba
J. Kanaya
Atsushi Shinohara
K. Koga
Mohamed F. Attallah
Jon Petter Omtvedt
Yoshitaka Kasamatsu
Atsushi Toyoshima
J. V. Kratz
Valeria Pershina
Yudai Shigekawa
Yukiko Komori
Matthias Schädel
M. Huang
D. Sato
Y. Kaneya
S. Tsuto
Y. Kitayama
Takuya Yokokita
M. Asai
Tatsuhiko Sato
N. Goto
Yoshihiro Kitatsuji
Kazuhiro Ooe
Akihiko Yokoyama
Kazuaki Tsukada
Source :
Journal of Radioanalytical and Nuclear Chemistry. 303:1317-1320
Publication Year :
2014
Publisher :
Springer Science and Business Media LLC, 2014.

Abstract

A new technique for continuous dissolution of nuclear reaction products transported by a gas-jet system was developed for superheavy element (SHE) chemistry. In this technique, a hydrophobic membrane is utilized to separate an aqueous phase from the gas phase. With this technique, the dissolution efficiencies of short-lived radionuclides of 91m,93mMo and 176W were measured. Yields of more than 80 % were observed for short-lived radionuclides at aqueous-phase flow rates of 0.1–0.4 mL/s. The gas flow-rate had no influence on the dissolution efficiency within the studied flow range of 1.0–2.0 L/min. These results show that this technique is applicable for on-line chemical studies of SHEs in the liquid phase.

Details

ISSN :
15882780 and 02365731
Volume :
303
Database :
OpenAIRE
Journal :
Journal of Radioanalytical and Nuclear Chemistry
Accession number :
edsair.doi...........c1988ee53e41ae04a720ca5994cea370