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The influence of oxidation process on exchange bias in egg-shaped FeO/Fe3O4 core/shell nanoparticles
- Source :
- Journal of Magnetism and Magnetic Materials. 416:269-274
- Publication Year :
- 2016
- Publisher :
- Elsevier BV, 2016.
-
Abstract
- Egg-shaped nanoparticles with a core–shell morphology were synthesized by thermal decomposition of an iron oleate complex. XRD and M(T) magnetic measurements confirmed the presence of FeO (wustite) and Fe3O4 (magnetite) phases in the nanoparticles. Oxidation of FeO to Fe3O4 was found to be the mechanism for the shell formation. As-made nanoparticles exhibited high values of exchange bias at 2 K. Oxidation led to decrease of exchange field from 2880 Oe (in as-made sample) to 330 Oe (in oxidized sample). At temperatures higher than the Neel temperature of FeO (200 K) there was no exchange bias. An interesting observation was made showing the exchange field to be higher than the coercive field at temperatures close to magnetite's Verwey transition.
- Subjects :
- Materials science
Thermal decomposition
Analytical chemistry
Nanoparticle
02 engineering and technology
engineering.material
Coercivity
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
01 natural sciences
0104 chemical sciences
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Charge ordering
Nuclear magnetic resonance
Exchange bias
chemistry
engineering
Wüstite
0210 nano-technology
Néel temperature
Magnetite
Subjects
Details
- ISSN :
- 03048853
- Volume :
- 416
- Database :
- OpenAIRE
- Journal :
- Journal of Magnetism and Magnetic Materials
- Accession number :
- edsair.doi...........c16727eb4709b706ad2ba5aca9b44d58