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Highly Efficient Recovery of Uranium from Seawater Using an Electrochemical Approach
- Source :
- Industrial & Engineering Chemistry Research. 57:8078-8084
- Publication Year :
- 2018
- Publisher :
- American Chemical Society (ACS), 2018.
-
Abstract
- Uranium recovery from seawater offers a promising route for producing scalable and sustainable nuclear energy because the world’s oceans contain hundreds of times more uranium than lands. A current adsorption method presents limitations including low extraction capacity and slow extraction kinetics, making realistic implementation impractical. Here we develop an electrochemical extraction approach that demonstrates high extraction capacity and fast extraction kinetics in uranium recovery. In the electrochemical approach, chitosan-functionalized electrodes were used to offer surface specific binding to uranyl ions; voltages were then supplied to attract the ions to the electrode and induce electrodeposition of uranyl ions to form charge-neutral uranium species. The electrodeposition approach demonstrated nearly 8 times higher uranium extraction capacities and 3 times faster extraction rates than the current adsorption method in uranium-spiked seawater. Because of the excellent uranium extraction performanc...
- Subjects :
- Materials science
General Chemical Engineering
Inorganic chemistry
Extraction (chemistry)
Kinetics
chemistry.chemical_element
02 engineering and technology
General Chemistry
Uranium
010402 general chemistry
021001 nanoscience & nanotechnology
Electrochemistry
Uranyl
01 natural sciences
Industrial and Manufacturing Engineering
0104 chemical sciences
Ion
chemistry.chemical_compound
chemistry
Electrode
Seawater
0210 nano-technology
Subjects
Details
- ISSN :
- 15205045 and 08885885
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Industrial & Engineering Chemistry Research
- Accession number :
- edsair.doi...........c0d48f57f5e1b1b426daa63e22c62fe6
- Full Text :
- https://doi.org/10.1021/acs.iecr.8b01063