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Di- and triphenylphosphonites of 2,2-di-(p-hydroxyphenyl)propane

Authors :
Yu. I. Blokhin
M. Ya. Érgashev
L. K. Vasyanina
E. E. Nifant'ev
Source :
Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:2205-2210
Publication Year :
1992
Publisher :
Springer Science and Business Media LLC, 1992.

Abstract

Starting from 2,2-di-(p-hydroxyphenyl)propane and phenylphosphonic acid tetraethylamide we have prepared the first oligoarylenephosphonites with spatially separated phosphorus functionalities. We have studied the principal chemical properties of these compounds. We have shown the capacity of oligoarylenediphosphonites to coordinate with transition metals through one or all phosphorus atoms with formation of mono- and oligo complexes. We have found that monocomplexes can undergo degenerated metallotropic rearrangements.

Details

ISSN :
15739171 and 10635211
Volume :
41
Database :
OpenAIRE
Journal :
Bulletin of the Russian Academy of Sciences Division of Chemical Science
Accession number :
edsair.doi...........c04585c6d131721cf1b649a620248437
Full Text :
https://doi.org/10.1007/bf01150748