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REACTIONS DE L'OZONE SUR DES MOLECULES PHOSPHOREES: OZONIDES

Authors :
F. El Khatib
Max Koenig
Anne-Marie Caminade
Source :
Phosphorus and Sulfur and the Related Elements. 14:381-383
Publication Year :
1983
Publisher :
Informa UK Limited, 1983.

Abstract

Ozone reacts very rapidly with alkylidenetriphenylphosphoranes 1a-d. In all cases we observed the cleavage of the P[dbnd]C bond and formation of triphenylphosphine oxide and the corresponding ketone 4a, 4b (R1 [dbnd] Ph) and alkene 4c (R1 [dbnd] H). Ozone also reacts with substituted phosphites 5a-b and gives the ozonides 7a-b.

Subjects

Subjects :
chemistry.chemical_classification
chemistry.chemical_compound
Ozone
Ketone
Chemistry
Alkene
Cleavage (embryo)
Photochemistry
Medicinal chemistry
Triphenylphosphine oxide

Details

ISSN :
0308664X
Volume :
14
Database :
OpenAIRE
Journal :
Phosphorus and Sulfur and the Related Elements
Accession number :
edsair.doi...........bff3b1796bdad65f6de339916d76f6c0
Full Text :
https://doi.org/10.1080/03086648308073271
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