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ChemInform Abstract: Cobalt(II) and Cobalt(III) Complexes of a Novel Homoleptic Thioether Cage
- Source :
- ChemInform. 23
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- Low-spin hexadentate cobalt(II) and cobalt(III) complexes of the hexathioether cage (1,8-dimethyl-3,6,10,13,16,19-hexathiabicyclo[6.6.6]icosarie) have been synthesised, their redox and spectral properties have been investigated, and the encapsulation of the cobalt(II) ion has been established by an X-ray crystal structure determination, which shows the metal ion to be coordinated to six thioether sulphur atoms at distances ranging from 2.265(3) to 2.354(2)A.
Details
- ISSN :
- 09317597
- Volume :
- 23
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........bf2b3020c90a9d66c19ad65396708e2c