In Situ Fenton-like Oxidation of Volatile Organics

Laboratory, pilot, and full-scale experiments were used to evaluate and optimize the ISOTECSM remedial process at a warehousing facility in Union, N. J. Based on modified Fenton’s oxidative chemistry, the ISOTEC SM process uses a proprietary catalytic agent which delays formation of reactive hydroxyl radicals. This allows adequate dispersion of the hydroxyl radicals, which is an oxidizing agent, throughout a contaminant plume. Groundwater at the site was contaminated with high levels of gasoline and waste oil constituents, principallybenzene, toluene, ethylebenzene, xylenes (BTEX) andmethyl-t-butylether (MTBE). Bench scale microcosm studies were used to evaluate the appropriate site-specific stoichiometric relationships between catalyst, stabilizers, and oxidizers; the effect of contaminant type and concentration; and the pH optima. Based on results of the laboratory studies, a pilot-scale study was performed at the site. One injection point for catalyst, stabilizers, and oxidant was installed in the contaminated zone at the site, with one hydraulically connected downgradient well used for monitoring. A single treatment of the reagents in the optimal stoichiometry determined from the laboratory study was injected in situ over a period of three days. A 98.5% reduction in volatile organics was observed in the area treated, with the radial extent of treatment estimated to be approximately 20 feet, based on the presence of hydroxyl radicals detected in hydraulically connected areas and at the surface. The full-scale process employed six injection points and three treatment cycles over a three month period. Subsequent to treatment, contaminant levels were either non-detectable or were reduced to below applicable New site. ISOTEC’s treatment activities were completed over several days within a six month period, with the case closed in under a year from start to finish.