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The C(sp3)–H bond functionalization of thioethers with styrenes with insight into the mechanism

Authors :
Zhan Yan
Nai-Xing Wang
Lei-Yang Zhang
Yue-Hua Wu
Jian-Li Li
Meng-Yao She
Xue-Wang Gao
Ke Feng
Yalan Xing
Source :
Organic & Biomolecular Chemistry. 20:5845-5851
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

Overcoming the low reactivity of thioethers, a C(sp3)–H bond functionalization of thioethers with styrenes using TBHP and DBU involving a radical relay process in metal-free conditions with theoretical questions elaborated is described.

Details

ISSN :
14770539 and 14770520
Volume :
20
Database :
OpenAIRE
Journal :
Organic & Biomolecular Chemistry
Accession number :
edsair.doi...........beadb76db36090b03e22a96fa6ab790b