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Molybdenum Complexes of C,C-Bis(ethynyl)carboranes: Design, Synthesis, and Study of a Weakly Coupled Mixed-Valence Compound

Authors :
Mark W. Whiteley
Mark A. Fox
Neil J. Brown
Hannah N. Lancashire
Dmitry S. Yufit
Ruth Edge
David Collison
Paul J. Low
Judith A. K. Howard
Source :
Organometallics. 30:884-894
Publication Year :
2010
Publisher :
American Chemical Society (ACS), 2010.

Abstract

The design and study of organometallic mixed-valence complexes is complicated by the mixing of metal d and bridging ligand π orbitals, which often makes the assignment of metal oxidation states amb...

Details

ISSN :
15206041 and 02767333
Volume :
30
Database :
OpenAIRE
Journal :
Organometallics
Accession number :
edsair.doi...........bde8666f305ab81cd79db7056914eb99
Full Text :
https://doi.org/10.1021/om1010353