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Facile Enantiodivergent Approach to 5-Hydroxy-5,6-dihydro-2(1H)-pyridones. First Total Synthesis of Both Enantiomers of Pipermethystine

Authors :
Ana Alcudia
Lanny S. Liebeskind
Ramon Gomez Arrayas
Source :
Organic Letters. 3:3381-3383
Publication Year :
2001
Publisher :
American Chemical Society (ACS), 2001.

Abstract

A novel enantiodivergent approach to 5-hydroxy-5,6-dihydro-2(1H)-pyridones using a ring closing metathesis and a lipase-mediated kinetic resolution as key steps is described and applied to the first synthesis of both enantiomers of pipermethystine.

Details

ISSN :
15237052 and 15237060
Volume :
3
Database :
OpenAIRE
Journal :
Organic Letters
Accession number :
edsair.doi...........bdb48e4965dc5f3cf9a80d21abd1600c
Full Text :
https://doi.org/10.1021/ol010183+