Total synthesis of the dibenzopyrrocoline alkaloid S-(+)-cryptaustoline. Revision of absolute configuration due to an unusual inversion in stereochemistry

Authors :: Thais M. Sielecki
Albert I. Meyers
Source :: Journal of the American Chemical Society. 113:2789-2790
Publication Year :: 1991
Publisher :: American Chemical Society (ACS), 1991.
Abstract: The natural alkaloid cryptaustoline is (13R,7S)-(−)-1 due to the heretofore unprecedented inversion while the formamidine route led to the expected (13S,7R)-(+)-1

Subjects :: chemistry.chemical_classification
Aldimine
Colloid and Surface Chemistry
Chemistry
Stereochemistry
Absolute configuration
Total synthesis
General Chemistry
Enantiomer
Biochemistry
Inversion (discrete mathematics)
Catalysis

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