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Preparation of Binuclear Octaethylporphinatoruthenium(II) Complexes Bridged with Diaza Compounds and Their Electrochemical Oxidation

Authors :
Kunio Shimizu
Jun-ichi Shimamura
Akira Endo
Gen P. Satô
Yosihiro Okamoto
Kaoru Suzuki
Source :
Chemistry Letters. 23:1317-1320
Publication Year :
1994
Publisher :
The Chemical Society of Japan, 1994.

Abstract

Binuclear octaethylporphinatoruthenium(II) complexes bridged with five diaza compounds (L), [{RuII(oep)(CO)}2(μ-L)] (H2oep = 2,3,7,8,12,13,17,18-octaethylporphin) have been synthesized. They are oxidized through two two-electron steps at a platinum electrode in CH2Cl2.

Details

ISSN :
13480715 and 03667022
Volume :
23
Database :
OpenAIRE
Journal :
Chemistry Letters
Accession number :
edsair.doi...........ba942bac00129a2147463b2b7b54570f