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Keggin type of polyoxometalate templated assembly of a silver-organic framework with silver-organic cages and helical structures
- Source :
- Inorganic Chemistry Communications. 93:153-159
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- A new POM-templated metal-organic framework [Ag8L4][PMo12O40]·OH {HL = 5-[4-(1,2,4-triazol-4-yl)phenyl]-1H-tetrazole} containing metal-organic nanocage and left- and right-handed helixes has been isolated under hydrothermal conditions. The Keggin POM plays a template role in the formation of macrocycle and metal-organic nanocage, as shown by X-ray diffraction analysis. The new compound represents a scarce example of POM-encapsulated metal-organic nanocage. Additionally, its photocatalytic degradation of RhB was also investigated.
Details
- ISSN :
- 13877003
- Volume :
- 93
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........b96abbecb375403d64dac29121ab56e0