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Pentafluorosulfanylated polymers as electrets in nonvolatile organic field-effect transistor memory devices
- Source :
- Journal of Materials Chemistry C. 7:7865-7871
- Publication Year :
- 2019
- Publisher :
- Royal Society of Chemistry (RSC), 2019.
-
Abstract
- The synthesis and characterization of a pair of pentafluorosulfanylated styrenic polymers and their subsequent application in nonvolatile organic field-effect transistor (OFET) memory devices are reported. The unusual pentafluorosulfanyl (SF5) functional group is unique in that it possesses a strong dipole moment that arises from both inductive and resonance effects but is at the same time highly hydrophobic. This intriguing chemical moiety also presents steric bulk that is comparable to a tert-butyl group. Exploiting these intrinsic physicochemical properties, the use of pentafluorosulfanylated styrenic polymers as the electret layer of nonvolatile OFET-based memory devices is reported. Aside from being the first examples of SF5-functionalized styrenic polymers, the reported materials also display excellent thermal stability, moderately large memory windows and retention times, and stable reversibilities spanning multiple PGM/ERS cycles.
- Subjects :
- chemistry.chemical_classification
Organic field-effect transistor
Materials science
business.industry
Transistor
02 engineering and technology
General Chemistry
Polymer
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
law.invention
chemistry.chemical_compound
Dipole
chemistry
Chemical Moiety
law
Functional group
Materials Chemistry
Optoelectronics
Thermal stability
Electret
0210 nano-technology
business
Subjects
Details
- ISSN :
- 20507534 and 20507526
- Volume :
- 7
- Database :
- OpenAIRE
- Journal :
- Journal of Materials Chemistry C
- Accession number :
- edsair.doi...........b7d4a542bde9e872ca9659a78a6487dc