ChemInform Abstract: Reversal of Stereoselectivity in the Cu-Catalyzed Conjugate Addition Reaction of Dialkylzinc to Cyclic Enone in the Presence of a Chiral Azolium Compound

Authors :: Satoshi Sakaguchi
Naoatsu Shibata
Yuko Yamamoto
Masaki Okamoto
Source :: ChemInform. 41
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: The addition of dialkylzinc to cyclic enones can give the (R)- and/or (S)-enantiomers using the same chiral ligand AZO but different Cu salts.

Subjects :: Addition reaction
chemistry.chemical_compound
Chemistry
Chiral ligand
Stereoselectivity
General Medicine
Enone
Medicinal chemistry
Conjugate
Catalysis

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